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Martin Minelli
Professor of Chemistry

Dr. Martin Minelli Office: S 2607
Phone: 641-269-3007
Email: minelli@grinnell.edu


Diplom, 1977, Staatsexamen (biology, chemistry, and physics), University of Konstanz.
Dr. 1980, rer. nat., University of Konstanz.
Postdoctoral research fellow 1981-84, University of Arizona.
Postdoctoral research fellow 1984-85, University of Konstanz.
University of Chicago, visiting associate professor, 1991/92.
Nanjing University, China, visiting professor, June 2004.
University of Konstanz, Germany, visiting professor, July 2004.
Sabbatical at the Max-Planck Institute for Bioinorganic Chemistry, Mülheim (Ruhr), fall 2005.

Research
Professor Minelli’s research deals with the synthesis and characterization of molybdenum compounds. Molybdenum compounds act as catalysts for a number of processes, among them olefin metathesis, and molybdenum is also a cofactor in biological systems. The study of these complexes helps to further the understanding of the role of molybdenum in the catalytic and biological field. Methods involved in this research are Schlenckline synthesis, multinuclear NMR spectroscopy, electrochemistry and X-ray crystallography (done off-campus).

[Full description PDF]

Courses
  • CHM 100 Chemistry is Everywhere
  • CHM 129 General Chemistry
  • CHM 130 Inorganic and Analytical Chemistry
  • CHM 423 Advanced Inorganic Chemistry
Recent Publications
  • Minelli, M. "Using 95Mo NMR spectroscopy in the Synthesis and Characterization of Mo(CO)6-n(CNR)n Complexes in Modern Nuclear Magnetic Resonance in Undergraduate Education." ACS Symposium Series Book, 2007, p.276-287.

  • Minelli, M.; Namuswe, F.; Jeffrey, D.; Morrow, A.; Guzei, I.A.; Swenson, D.; Bothe, E.; Weyhermüller, T. "Synthesis, Structure and Characterization of Molybdenum(VI) Imido Complexes with N-salicylidene-2-aminophenol." Inorg. Chem. 2006, 45, 5455-64.

  • Minelli, M.; Hoang, M.L.; Kraus, M.; Kucera, G.; Loertscher, J.; Reynolds, M.; Timm, N.; Chiang, M.Y.; Powell, D. "The effect of Substituents on the Phenyl Portion of the Imido Ligand on the Structure and Properties of Mo(VI) Imido Complexes." Inorg. Chem. 2002, 41, 5954.

  • Minelli, M.; Kuhlman, R.L.; Shaffer, S.J.; Chiang, M. "Synthesis, Structure and Characterization of the Diimido-bridged Bimetallic Molybdenum(V) Complex Bis(diethyldithiocarbamato)bis(2-_-aminothiophenolato) oxodimolybdenum(V)-Bis(dichloromethane), (dtc)MoO(_-NC6H4S)2 Mo(dtc).2CH2Cl2 and of the Precursor in the Formation of this bimetallic Molybdenum(V) Complex, Bis(diethyldithiocarbamato) (2-aminothio- phenolato)(methoxy)molybdenum(VI), Mo(NC6H4S)(OCH3)(dtc)2." Inorg. Chem. 1992,31, 3891.

  • Minelli, M.; Carson, M.R.; Whisenhunt Jr., D.W.; Imhof, W.; Huttner, G. "Synthesis, Structure and Characterization of dichlorobis(diethyl-dithiocarbamato)2-mercaptophenylimidomolybdenum(VI)." Inorg. Chem. 1990, 29, 4801.


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